报告时间：2014年6月19日（星期四）上午10:00-11:30
报告地点：东区资源环境楼一楼学术报告厅
Frontiers on Metallocene Polymers: from Controlled Polymerization to Electrolyte Chemistry to Medicinal Chemistry
Chuanbing Tang
Department of Chemistry and Biochemistry, University of South Carolina
Metallopolymers combine synthetic efficiency and versatility of an organic polymer framework with unique properties of inorganic metals. Among them, metallocene-containing polymers play a significant role in materials science due to their thermal stability, reversible redox chemistry and many other fascinating properties that arise from their sandwich-like structures. After nearly half-century development, the field of metallocene-containing polymers faces numerous challenges. This presentation will highlight recent progress developed by my group in the synthesis and applications of metallocene-containing polymers with diverse architectures by controlled polymerization techniques such as reversible addition fragmentation transfer polymerization (RAFT) and ring-opening metathesis polymerization (ROMP). Both polyelectrolyte chemistry and robust template synthesis toward versatile advanced cobalt materials will be covered. Medicinal applications of these metallopolymers as antimicrobial agents and their bioconjugates with conventional antibiotics for fighting bacterial resistance will be discussed.
References:
1. Ren L.; Hardy C. G.; Tang C. Synthesis and Solution Self-assembly of Side-Chain Cobaltocenium-containing Block Copolymers, J. Am. Chem. Soc., 2010, 132, 8874-8875.
2. Ren L.; Zhang J.; Bai X.; Hardy C. G.; Shimizu K. D.; Tang C. Preparation of Cationic Cobaltocenium Polymers and Block Copolymers by “Living” Ring-Opening Metathesis Polymerization. Chem. Sci. 2012, 3, 580-583.
3. Zhang J.; Yan Y.; Chance W. M.; Chen J.; Hayat J.; Ma S.; Tang C. Charged Metallopolymers as Universal Precursors for Versatile Cobalt Materials, Angew. Chem. Int. Ed. 2013, 52, 13387 –133.
Chuanbing Tang
Department of Chemistry and Biochemistry, University of South Carolina
631 Sumter Street, Columbia, SC 29208
Tel: 803-777-3628; Fax: 803-777-8100; Email: tang4@mailbox.sc.edu;
URL: http://www.chem.sc.edu/faculty/tang
Education
2006 Ph.D. Chemistry, Carnegie Mellon University
Advisors – Prof. Krzysztof Matyjaszewski and Prof. Tomasz Kowalewski
1997 B.S. Polymer Science and Engineering, Nanjing University
Advisor – Prof. Rongshi Cheng
Professional Experience
Aug 2014- College of Arts and Sciences Distinguished Professor, Department of
Chemistry and Biochemistry, University of South Carolina
June 2014- Associate Professor, Department of Chemistry and Biochemistry,
University of South Carolina
Aug 2009-June 2014 Assistant Professor, Department of Chemistry and Biochemistry,
University of South Carolina
June 2006-July 2009 Postdoctoral Scholar, University of California Santa Barbara
Advisors – Prof. Edward J. Kramer and Prof. Craig J. Hawker
Awards and Honor
Nominated for ACS ChemLuminary Award (2014)
Nominated for USC Ada B. Thomas Outstanding Faculty/Staff Advisor Award (2014)
Nominated for USC Distinguished Undergraduate Research Mentor Award (2014)
ACS PMSE Young Investigator (2014)
USC NIH CAM Pilot Project Award (2013)
USC Rising Star (2013)
NSF Career Award (2013-2018)
Thieme Chemistry Journal Award (2013)
ACS Leadership Development Award Alternate (2013)
Guest Editor on a Themed Issue on “Next-Generation Renewable Polymers” by “Green Materials” (2013)
Invited on ‘Emerging Investigators’ Issue by “Chemical Communications” (2013)
ACS Committee on Project Seed (2012-2015)
ACS PRF Doctoral New Investigator Award (2012)
Editorial Boards for PLOS One, Green Materials (Since 2013), International Journal of Polymeric Materials (Since 2012), and ISRN Polymer Science (Since 2011)
USDA US-China Agriculture Scientific Exchange Team (2011)
USC Magellan Scholar Award (Undergraduate Research, 2010, 2011, 2013)
Singapore National Research Foundation Research Fellow (2009)
UC Santa Barbara Materials Research Outreach Program Best Poster Prize (2008)
Chinese Government Award for Outstanding Students Abroad (2005)
ACS R. A. Glenn Award Finalist (2005)
ACS Pittsburgh Section Polymer Group Student Award (2005)
Research Interest
Themes: Organic synthetic polymer chemistry interfaced with medicinal chemistry and
advanced materials.
Green chemicals and monomers from biomass and sustainable polymers; organometallic
compounds and polymers; medicinal chemistry; novel antimicrobial agent design; block
copolymer self-assembly for lithography, nanoparticles and energy storage.
Peer-Reviewed Publications
Publications as PI at University of South Carolina
(75) Qiao Y.; Ferebee R.; Lee B.; Mitra I.; Lynd N. A.; Hayat J.; Stein G.;* Bockstaller M.
R.;* Tang C.* Symmetric Poly(ethylene oxide-b-styrene-b-isoprene) Triblock
Terpolymers: Synthesis, Characterization and Self-Assembly in Bulk and Thin Film.
Macromolecules 2014, submitted.
(74) Li H.; Huang Y.; Wang L.; Qiao Y.; Tang C.; Jung C.; Yoon Y.; Yu M.* Graphene
Oxide Membranes with Hierarchical Roughness for Anti-Fouling Oil/Water Separation.
Adv. Mater. 2014, submitted.
(73) Hayat J.; Mitra I.; Hardy C. G.; Stein G.;*, Tang C.* Addressing Two Challenges in
Solvent Annealing Processes for Block Copolymers. Polymer 2014, submitted..
(72) Yan Y.; Zhang J.; Wilbon P.; Qiao Y.; Tang C.* Facile synthesis of side chain
18-electron cobalt(I)-containing polymer via ROMP and its use as a heterogeneous catalyst
in ATRP. 2014, in preparation.
(71) Qiao Y.; Islam M. S.; Wang L.; Yan Y.; Zhang J.; Benicewicz B. C.; Ploehn H. J.*;
Tang C.* Oligothiophene Polymer-Grafted Barium Titanate Nanoparticles for
Nanodielectric Energy Storage. Adv. Energy Mater. 2014, submitted.
(70) Wei J.; Ren L.; Tang C.; Su Z.* Electric-stimulus-responsive Multilayer Film Based
on Cobaltocenium-containing Polymer. Macromolecules 2014, submitted.
(69) Zhang J.; Yan Y.; Chen J.; Chance M.; Hayat J.; Gai Z.; Tang C.* Nanostructured
Metal/Carbon Composites from Heterobimetallic Block Copolymers with Controlled
Magnetic Properties. Chem. Mater. 2014, DOI: 10.1021/cm5007058.
(68) Zhang J.; Chen Y.-P.; Miller K. P.; Ganewatta M. S. Bam M.; Yan Y.; Nagarkatti
M.; Decho A. W.; Tang C.* Antimicrobial Metallopolymers and Their Bioconjugates
with Antibiotics against Multidrug Resistant Bacteria, J. Am. Chem. Soc. 2014, 136,
4873-4876.
(67) Hardy C. G.; Zhang J.; Yan Y.; Ren L.; Tang C.* Metallopolymers with Transition
Metal in Side Chain by Living and Controlled Polymerization Techniques, Prog. Polym.
Sci. 2014, DOI: 10.1016/j.progpolymsci.2014.03.002.
(66) Ganewatta M. S.; Chen Y.-P.; Wang J.; Zhou J.; Ebalunde J.; Nagarkatti M.; Decho
A. W.*; Tang C.* Bio-inspired Resin Acid-Derived Materials as Anti-Bacterial
Resistance Agents with Unexpected Activities. Chem. Sci., 2014, 5, 2011 - 2016.
(65) Liu Y.; Yao K.; Chen X.; Wang J.; Wang J.; Ploehn H.; Wang C.; Chu F.; Tang C.*
Sustainable Thermoplastic Elastomers Derived from Renewable Cellulose, Rosin and
Fatty Acids, Polym. Chem. 2014, 5, 3170 - 3181. Inside Front Cover
(64) Zhong M.; Tang C.;* Kim E. K.; Kruk M.; Celer E. B.; Jaroniec M.; Matyjaszewski
K.;* Kowalewski T.* Preparation of porous nanocarbons with tunable morphology and
pore size from copolymer templated precursors. Mater. Horiz., 2014, 1, 121-124.
(63) Yu J.; Liu Y.; Liu X.; Wang C.; Wang J.*; Chu F.*; Tang C.* Integration of
Renewable Cellulose and Rosin towards Sustainable Copolymers by “Grafting From”
ATRP, Green Chem. 2014, 16, 1854-1864.
(62) Yan Y.; Zhang J.; Qiao Y.; Tang C.* Facile Preparation of
Cobaltocenium-containing Polyelectrolyte via Click Chemistry and RAFT
Polymerization, Macromol. Rapid Commun. 2014, 35, 254-259.
(61) Yan Y.; Zhang J.; Qiao Y.; Ganewatta M. S.; Tang C.* Ruthenocene-containing
Homopolymers and Block Copolymers via ATRP and RAFT Polymerization.
Macromolecules, 2013, 46, 8816-8823.
(60) Zhang J.; Yan Y.; Chance W. M.; Chen J.; Hayat J.; Ma S.; Tang C.* Charged
Metallopolymers as Universal Precursors for Versatile Cobalt Materials, Angew. Chem. Int.
Ed. 2013, 52, 13387 –13391.
(59) Jiang F.; Wang Z.; Qiao Y.; Wang Z. G.*; Tang C.* A Novel Architecture toward
3rd-Generation Thermoplastic Elastomers by a Grafting Strategy, Macromolecules 2013,
46, 4772–4780.
(58) Qiao Y.; Islam M. D.; Han G.; Leonhardt E.; Zhang J.; Wang Q.; Ploehn H. J.; Tang
C.* Polymers Containing Highly Polarizable Conjugated Side Chains as High
Performance All-Organic Nanodielectric Materials, Adv. Funct. Mater., 2013, 23,
5638–5646. Inside Front Cover
(57) Wang J.; Yao K.; Wang C.; Tang C.*; Jiang X.* Synthesis and Drug Delivery of
Novel Amphiphilic Block Copolymers Containing Hydrophobic Dehydroabietic Moiety. J.
Mater. Chem. B, 2013, 1, 2324-2332.
(56) Yao K.; Chen Y.; Zhang J.; Bunyard C.; Tang C.* Cationic Salt-Responsive
Bottle-Brush Polymers. Macromol. Rapid Commun. 2013, 34, 645-651. Cover
(55) Tang C.* Editorial: Next-Generation Renewable Polymers (Speical Issue on
Renewable Polymers), Green Materials 2013, 1, 62-63.
(54) Yao K.; Tang C.* Controlled Polymerization of Next-Generation Renewable
Monomers and Beyond. Macromolecules (Perspective) 2013, 46, 1689-1712. Cover.
(53) Hardy C. G.; Islam M. S.; Gonzalez-Delozier D.; Morgan J. E.; Cash B.; Benicewicz
B. C.; Ploehn H. J., Tang C.* Converting an Electrical Insulator into a Dielectric Capacitor:
End-Capping Polystyrene with Oligoaniline. Chem. Mater. 2013, 25, 799-807.
(52) Zhang J.; Pellechia P. J.; Hayat J.; Tang C.* Quantitative and Qualitative Counterion
Exchange in Cationic Metallocene Polyelectrolytes. Macromolecules 2013, 46,
1618-1624.
(51) Wilbon P.; Gulledge A. L.; Benicewicz B. C.; Tang C.* Renewable Rosin-Fatty Acid
Polyesters: the Effect of Backbone Structure on Thermal Properties. Green Materials 2013,
1, 96-104.
(50) Wang J.; Yu J.; Liu Y.; Chen Y.; Wang C.; Tang C.; Chu F.* Synthesis and
Characterization of a Novel Rosin-Based Monomer: Free Radical Polymerization and
Epoxy Curing, Green Materials 2013, 1, 105-113.
(49) Hardy C. G.; Ren L.; Ma S.; Tang C.* Self-Assembly of Well-Defined Ferrocene
Triblock Copolymers and Their Template Synthesis of Ordered Iron Oxide Nanoparticles.
Chem. Commun. 2013, 49, 4373-4375. Invited original article for the 2013 “Emerging
Investigators” issue.
(48) Ko N. R.; Yao K.; Tang C.; Oh J. K.*, Synthesis and thiol-responsive degradation of
polylactide-based bock copolymers having disulfide junctions using ATRP and ROP. J.
Polym. Sci. Part A: Polym. Chem. 2013, 51, 3071-3080.
(47) Zhang W.; Zhao S.; Rao W.; Snyder J.; Choi J. K.; Wang J.; Khan I. A.; Saleh N. B.;
Mohler P. J.; Yu J.; Hund T. J.; Tang C.; He X.* A Novel Core-Shell Microcapsule for
Encapsulation and 3D Culture of Embryonic Stem Cells. J. Mater. Chem. B, 2013, 1,
1002-1009.
(46) Chen Y.; Wilbon P.; Zhou J.; Nagarkatti M.; Wang C.; Chu F.; Tang C.*
Multifunctional Self-Fluorescent Polymer Nanogels for Label-free Imaging and Drug
Delivery. Chem. Commun. 2013, 49, 297-299.
(45) Hardy C. G.; Tang C.* Advances in Square Arrays through Self-Assembly and
Directed Self-Assembly of Block Copolymers. J. Polym. Sci. Polym. Phys. (Invited review
article), 2013, 51, 2-15. Cover
(44) Yao K.; Tang C.*; Zhang J.; Bunyard C. Degradable and Salt-Responsive Random
Copolymers. Polym. Chem. 2013, 4, 528-535.
(43) Wilbon P.; Chu F*.; Tang C.*; Progress in Renewable Polymers from Natural
Terpenes, Terpenoids and Rosin. Macromol. Rapid Commun. (review article), 2013, 34,
8-37. Cover
(42) Zhang J.; Ren L.; Hardy C. G.; Tang C.* Cobaltocenium-containing Methacrylate
Homopolymers, Block Copolymers and Heterobimetallic Polymers via RAFT
Polymerization. Macromolecules, 2012, 45, 6857-6863.
(41) Chen Y.; Wilbon P. A.; Chen Y. P.; Zhou J.; Nagarkatti M.; Wang C.; Chu F.; Decho
A. W.; Tang C.* Amphipathic Antibacterial Agents Using Cationic Methacrylic Polymers
with Natural Rosin as Pendant Group. RSC Adv., 2012, 2, 10275-10282.
(40) Ren L.; Zhang J.; Doxie D.; Fleming B.; Hardy C. G.; Tang C.* Preparation of
Cobaltocenium-labeled Polymers by Atom Transfer Radical Polymerization.
Macromolecules, 2012, 45, 2267-2275.
(39) Hardy C. G.; Islam M. S.; Gonzalez-Delozier D.; Ploehn H.J.,* Tang C.*
Oligoaniline-Containing Supramolecular Block Copolymers as Nanodielectric Materials.
Macromol. Rapid Commun. 2012, 33, 791-797. Invited article for special issue “Polymer
Science: the next Generation”.
(38) Ren L.; Zhang J.; Hardy C. G.; Ma S.; Tang C.* Cobaltocenium-containing Block
Copolymers: Ring-opening Metathesis Polymerization, Self-assembly and Template
synthesis of Inorganic Nanoparticles. Macromol. Rapid Commun. 2012, 33, 510-516.
Invited article for special issue “Metal-Containing and Metallo-Supramolecular Polymers
and Materials”.
(37) Wang J.; Chen Y. P.; Yao K.; Wilbon P. A.; Zhang W.; Ren L.; Zhou J.; Nagarkatti M.;
Wang C.; Chu F.; He X.; Decho A. W.; Tang C.* Robust Antimicrobial Compounds and
Polymers Derived from Natural Resin Acids. Chem. Commun. 2012, 48, 916-918.
(36) Ren L.; Zhang J.; Bai X.; Hardy C. G.; Shimizu K. D.; Tang C.* Preparation of
Cationic Cobaltocenium Polymers and Block Copolymers by “Living” Ring-Opening
Metathesis Polymerization. Chem. Sci. 2012, 3, 580-583.
(35) Korich A. L.; Fleming A. B.; Walker A. R.; Wang J.; Tang C.; Iovine P. M. Chemical
Modification of Organosolv Lignin Using Arylboronic Acid-Containing Reagents.
Polymer. 2012, 53, 87-93.
(34) Hardy C. G.; Ren L.; Zhang J.; Tang C.* Side-Chain Metallocene-Containing
Polymers by Living and Controlled Polymerizations. Israel J. Chem. 2012, 52,230-245
(Invited review article).
(33) Wang J.; Yao K.; Wilbon P.; Wang P.; Chu F.; Tang C.* Rosin-Derived Polymers
and Their Progress in Controlled Polymerization, in “Rosin-based Chemicals and
Polymers” Zhang J., Ed.; ISmithers. Shawbury, UK, 2012, 85-127 (Invited Book Chapter).
(32) Tang C.*; Wu W.; Smilgies D-M.; Matyjaszewski K.; Kowalewski T. Robust Control
of Long-Range Order in Thin Films of Block Copolymers by Zone Casting. J. Am. Chem.
Soc. 2011, 130, 11802-11809.
(31) Wang J.; Yao K.; Korich A.; Li G.; Ma S.; Ploehn H.; Iovine P.; Wang C.; Chu F.;
Tang C.* Combining Renewable Gum Rosin and Lignin: Towards Hydrophobic Polymer
Composites by Controlled Polymerization. J. Polym. Sci. Polym. Chem., 2011, 49,
3728-3738.
(30) Yao K.; Wang J.; Zhang W.; Lee, J. S.; Wang C.; Chu F.; He X.; Tang C.*
Degradable Rosin Ester-Caprolactone Graft Copolymers, Biomacromolecules, 2011, 12,
2171-2177.
(29) Hardy C. G.; Ren L.; Tamboue T. C.; Tang C.* Side-chain Ferrocene-Containing
(Meth)Acrylate Polymers: Synthesis And Properties. J. Polym. Sci. Polym. Chem., 2011,
49, 1409-1420.
(28) Ren L.; Hardy C. G.; Tang S.; Doxie D. B.; Hamidi N.; Tang C.* Preparation of
Side-Chain 18-e Cobaltocenium-Containing Vinyl Monomers And Polymers,
Macromolecules, 2010, 43, 9304-9310.
(27) Wilbon P. A.; Zheng Y.; Yao K.; Tang C.* Renewable Rosin Acid-Degradable
Caprolactone Block Copolymers by Atom Transfer Radical Polymerization And
Ring-Opening Polymerization, Macromolecules, 2010, 43, 8747-8754.
(26) Zheng Y.; Yao K.; Lee J. S.; Chandler D.; Wang J.; Wang C.; Chu F.; Tang C.*
Well-defined Renewable Polymers Derived From Gum Rosin, Macromolecules, 2010, 43,
5922-5924.
(25) Ren L.; Hardy C. G.; Tang C.* Synthesis and Solution Self-Assembly of Side-Chain
Cobaltocenium-Containing Block Copolymers, J. Am. Chem. Soc. 2010, 132, 8874-8875.
(24) Tang C.*; Hur S.; Stahl, B. C.; Sivanandan K.; Dimitriou M.; Pressly E.; Fredrickson
G. H.; Kramer E. J.; Hawker C. J. Thin Film Morphology of Block Copolymer Blends
with Tunable Supramolecular Interactions for Lithographic Applications.
Macromolecules, 2010, 43, 2880-2889.
Postdoctoral/Graduate/Undergraduate Publications
(23) Tang C.; Sivanandan K.; Brian C. Stahl, Fredrickson G. H.; Kramer E. J.; Hawker C.
J. Multiple Nanoscale Templates by Orthogonal Degradation of a Supramolecular Block
Copolymer Lithographic System. ACS Nano, 2010, 4, 285-291.
(22) Tang C.; Lennon E. M.; Fredrickson G. H.; Kramer E. J.; Hawker C. J. Evolution of
Block Copolymer Lithography to Highly Ordered Square Arrays. Science, 2008, 322,
429-432.
(21) Takizawa K.; Tang C.; Hawker C. J. Molecularly Defined Caprolactone Oligomers
and Polymers: Synthesis and Characterization. J. Am. Chem. Soc., 2008, 130, 1718-1726.
(20) Tang C.; Bang J.; Stein, G.; Fredrickson G. H.; Hawker C. J.; Kramer E. J. Square
Packing and Structural Arrangement of ABC Triblock Copolymer Spheres in Thin Films.
Macromolecules, 2008, 41, 4328-4339.
(19) Tang C.; Bombalski L.; Kruk M.; Jaroniec M.; Matyjaszewski K.; Kowalewski K.
Nanoporous Carbon Films from “Hairy” Polyacrylonitrile-Grafted Colloidal Silica
Nanoparticles. Adv. Mater., 2008, 20, 1516-1522.
(18) Korth, B.D.; Keng, P.; Shim. I.; Tang, C.; Kowalewski, T.; Pyun, J. Synthesis,
Assembly and Functionalization of Polymer Coated Ferromagnetic Nanoparticles, in
“Nanoparticles: Synthesis, Stabilization, Passivation and Functionalization, ACS
Symposium Series. Nagarajan R. and Hatton T. A. Eds. American Chemical Society:
Washington, DC. 2008, 996, 272-285.
(17) Dufour B.; Tang C.; Koynov K.; Zhang Y.; Pakula T.; Matyjaszewski K. Polar 3-Arm
Star Block Copolymer Thermoplastic Elastomers. Macromolecules, 2008, 41, 2451-2458.
(16) Bombalski L.; Min K.; Dong, H.; Tang C.; Matyjaszewski K. Preparation of
Well-Defined Hybrid Materials by ATRP in Miniemulsion. Macromolecules, 2007, 40,
7429-7432.
(15) Tang C.; Dufour B.; Kowalewski T.; Matyjaszewski K. Synthesis and Morphology of
Molecular Brushes with Polyacrylonitrile Block Copolymer Side Chains and Their
Conversion Into Nanostructured Carbons. Macromolecules, 2007, 40, 6199-6205.
(14) Kruk M.; Tang C.; Dufour B.; Matyjaszewski K.; Kowalewski T. Nanostructured
Carbons from Block Copolymers, in Block Copolymers in Nanoscience, Lazzari M.; Liu
G.J.; Lecommandoux S. Eds. Wiley-VCH: Weinheim, 2007, 257-274.
(13) Huang J.; Tang C.; Lee, H-i.; Kowalewski T.; Matyjaszewski K. A Novel Route for
the Preparation of Discrete Nanostructured Carbons from Block Copolymers with
Polystyrene Segments. Macromol. Chem. Phys., 2007, 208, 2312-2320.
(12) McCullough L. A.; Dufour B.; Tang C.; Zhang Y.; Pakula T.: Kowalewski T.;
Matyjaszewski K. Templating Conducting Polymers via Self-Assembly of Block
Copolymers and Supramolecular Recognition. Macromolecules, 2007, 40, 7745-7747.
(11) Korth B. D.; Keng P.; Shim, I.; Bowles S. E.; Tang C.; Kowalewski T.; Nebesny K.
W.; Pyun J. Polymer-coated Ferromagnetic Colloids from Well-Defined Macromolecular
Surfactants and Assembly into Nanoparticle Chains. J. Am. Chem. Soc., 2006, 128,
6562-6563.
(10) Oh J. K.; Tang C.; Gao H.; Tsarevsky N. V.; Matyjaszewski K. Inverse
Miniemulsion ATRP: A New Method for Synthesis and Functionalization of
Well-Defined Water-Soluble/Cross-Linked Polymeric Particles. J. Am. Chem. Soc., 2006,
128, 5578-5584.
(9) Kowalewski T.; Tang C.; Kruk M.; Dufour B.; Matyjaszewski K. Advances in
Nanostructured Carbons from Block Copolymers Prepared by Controlled Radical
Polymerization Techniques, in Controlled/Living Radical Polymerization: From Synthesis
to Materials, ACS Symposium Series. Matyjaszewski K. Ed. American Chemical Society:
Washington, DC. 2006, 944, 295-310.
(8) Tang C.; Tracz A.; Kruk M.; Zhang R.; Smiligies D.; Matyjaszewski K.; Kowalewski
T. Long-range Ordered Thin Films of Block Copolymers Prepared by Zone-Casting and
Thermal Conversion into Ordered Nanostructured Carbon. J. Am. Chem. Soc., 2005, 127,
6918-6919.
(7) Pyun J.; Tang C.; Kowalewski T.; Fréchet J.M.J.; Hawker C. J. Synthesis of
Particle-Coil Block Copolymers: A New Class of Block Copolymer from Linear and
Dendritic Precursors. Macromolecules, 2005, 38, 2674-2685.
(6) Tang C.; Qi K.; Wooley K.; Matyjaszewski K.; Kowalewski T. Well-defined Carbon
Nanoparticles Prepared from Water Soluble Shell Cross-Linked Micelles Containing
Polyacrylonitrile Cores. Angew. Chem. Int. Ed, 2004, 43, 2783-2787; Angewandte Chemie,
2004, 116, 2843-2847.
(5) Tang C.; Kowalewski T.; Matyjaszewski K. RAFT Polymerization of Acrylonitrile
and Preparation of Block Copolymers Using 2-Cyanoethyl Dithiobenzoate as the Transfer
Agent. Macromolecules, 2003, 36, 8587-8589.
(4) Tang C.; Kowalewski T.; Matyjaszewski K. Preparation of
Polyacrylonitrile-b-Poly(n-Butyl Acrylate) Copolymers Using Atom Transfer Radical
Polymerization and Nitroxide Mediated Polymerization Processes. Macromolecules 2003,
36, 1465-1473.
(3) Tang C.; Chu F. Semicontinuous Emulsion Polymerization of Styrene-Butyl
Acrylate-Methacrylic Acid with High Solid Content. J. Appl. Polym. Sci., 2001, 82,
2352-2356.
(2) Tang C.; Chu F. Morphology of Core-Shell Hybrid Latex Particles. China Adhesives
(in Chinese) 2001, 10(6), 30-35.
(1) Chu F.; Tang C.; Alain G. Study on High Solid Polydisperse Particle Size Distribution
Polymer Emulsion (2) - Preparation of Binary-Disperse Particle Size Distribution
Emulsion by Two Seeds Method. Technology on Adhesion & Sealing (in Chinese) 2000,
21(2), 1-3, 9.
Patents and Applications
(9) Tang C.; Hardy C.; Nese A.; Hayat J. Multiple Copolymer Systems as Templates for
Block Copolymer Nanolithography, U.S. Provisional Patent Application, Serial No.
61/962,461.
(8) Tang C.; Zhang J.; Chen Y. P.; Decho A. W. Metallocene-containing cationic
compounds and polymers loaded with antibiotics as antimicrobial agents, U.S. Provisional
Patent Application, Serial No. 61/961, 527.
(7) Tang C.; Zhang J.; Chen Y. P.; Decho A. W. Anion-paired cationic
metallocene-containing compounds and polymers as antimicrobial agents, U.S.
Provisional Patent Application, Serial No. 61/808, 436.
(6) Tang C.; Qiao Y.; Ploehn H. J.; Islam M. S. Preparation of conjugated
aromatic/heteroaromatic oligomer-containing dielectric polymers and their applications,
U.S. Provisional Patent Application, Serial No. 61/755,155.
(5) Tang C.; Yao K. Compositions of Degradable Salt-Responsive Copolymers. U.S.
Provisional Patent Application, Serial No. 61/690,521.
(4) Tang C.; Wang J.; Decho A. W.; Chen Y. P. Rosin-Derived Cationic Compounds and
Polymers along with Their Methods of Preparation, U.S. Patent 8,604,128.
(3) Tang C.; Ren L. Preparation of Cobaltocenium-Containing Monomers and Their
Polymers for Electrodes Use, US Patent 8,592,539.
(2) Tang C. Polymers Derived from Rosin and Their Methods of Preparation, US Patent
8,569,427.
(1) Hawker C. J.; Tang C.; Kramer, E. J.; Fredrickson, G. H. Supramolecular Block
Copolymer Compositions for Sub-Micron Lithography, PCT Int. Appl. WO 2009151834.
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