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蔡远利教授学术报告

( 2011-02-28 )
 

报告题目

Visible Light Activated Room Temperature RAFT Polymerization

报告时间

201134 (星期五) 上午10:00

报告地点

材料楼五楼会议室

报告摘要

报告人

蔡远利教授(湘潭大学)

 
蔡远利,1967 年9 月出生,湖南华容人,博士,教授,博士生导师,湖南省新
世纪121 人才工程第二层次人选,湖南省高校优秀青年骨干教师,环境友好化学与应
用教育部重点实验室学术委员会委员,科技部国际科技合作计划项目评价专家,湖南
省化学化工学会高分子学科专业委员会委员。

2001 年,毕业于中国科学院化学研究所,获理学博士学位。2001-2002 年,德
国Bayreuth 大学博士后。2002-2004 年,英国Sussex 大学、Sheffield 大学博士
后。2005 年,加拿大Montréal 大学访问研究。2004 年回国,效力于湘潭大学,校
聘教授。2005 年晋升为教授。2006 年获博士生导师资格。2005 年12 月至今,担
任湘潭大学化学学院副院长。
近年来,致力于模仿生物大分子的精细合成与操控,探索温和条件下有机高分子
的精确合成与环境调控自组织。近5 年,主持国家自然科学基金3 项,教育部博士点
基金及其它项目5 项。在JACS, ChemComm, Macromolecules 等刊物发表SCI
收录论文47 篇,SCI 影响因子3.0 以上知名刊物论文32 篇。2004 年以来,每年均
在Macromolecules 发表论文。他人引用500 多次,单篇他引50 次以上的论文4 篇,
10 次以上的论文13 篇。获授权国家发明专利2 项,中国分析测试协会科学技术一等
奖1 项。创建了可见光活化室温RAFT 聚合新方法,被国内外学者誉为可控自由基聚
合的最新进展之一。
2007 年,担任IUPAC 先进材料与合成研讨会分会主席,并作邀请报告。2008
年,在国家自然科学基金委化学部高分子合成化学前沿科学问题研讨会上报告《环境
友好的活性/可控自由基聚合-机遇与挑战》。2009 年,在全国高分子学术论文报告
会作《环境友好与快速高效的可见光活化室温RAFT 聚合》邀请报告。2010 年,应
邀为《化学进展》“绿色有机合成化学专辑”特约评述《环境友好的可控自由基聚合》,
获Macromolecules 刊物Top 25%稿件评审专家。
回国以来,培养毕业博士生2 名,硕士生16 名。1 名博士生获湖南省第十一届
自然科学优秀学术论文一等奖,2 名硕士生获湖南省优秀硕士学位论文奖,1 名硕士生
获校长特等奖,4 名硕士生获校长优秀奖。
【主持项目】
􀂗 国家自然科学基金面上项目【21074104】具有选择性配位和动态交换特性的聚合物胶束的设计
构筑,经费39 万元,执行年限2011.01-2013.12
􀂗 国家自然科学基金面上项目【20874081】希夫碱和环缩醛类光敏单体的设计合成及其可见光活
化室温RAFT 聚合,经费34 万元,执行年限2009.01-2011.12
􀂗 国家自然科学基金面上项目【20674064】近紫外及可见光照下的快速可控室温RAFT 聚合,
经费28 万元,执行年限:2007.01-2009.12,已结题
􀂗 高等学校博士学科点专项科研基金【200805300004】光响应高分子仿生材料的分子设计与环境
友好合成,经费6 万元,执行年限2009.01 - 2011.12
􀂗 湖南省教育厅科研基金重点项目【10A116】金属配位调控聚合物胶束的仿生设计与构筑,经费
8 万元,执行年限:2010.09-2013.08
􀂗 湖南省教育厅科研基金优秀青年项目【06B090】快速可控和环境友好的光活化室温可逆加成断
裂链转移自由基聚合,经费4 万元,执行年限:2007.01-2009.12,已结题
􀂗 教育部留学回国人员科研启动基金【教外司 2005-383】壳聚糖基水溶性智能柱状高分子刷的
合成、超分子构筑及环境响应特性,经费2.5 万元,执行年限:2005.01-2007.12,已结题
􀂗 湖南省自然科学基金【05JJ40023】结构规整的壳聚糖基水溶性智能高分子刷的合成及其对环
境响应特性研究,经费2 万元,执行年限:2005.01-2007.12,已结题
【主讲课程】
本科生:专业英语,高分子物理,高分子科学进展
硕士研究生:高分子物理及实验
博士研究生:高分子化学进展
【主要论文】
1) 蔡远利* 卢礼灿 姜稳定 张海佳 邓俊杰 李瑶华 石毅,环境友好的可控自由基聚合,化学进
展(“绿色有机合成化学专辑”特约稿)2010, 22(7), 1490-1498.
2) Chaowei Cao, Ke Yang, Fen Wu, Xiangqian Wei, Lican Lu, Yuanli Cai*, Thermally
Induced Swellability and Acid-Liable Dynamic Properties of Microgels of Copolymers
Based on PEGMA and Aldehyde-Functionalized Monomer, Macromolecules 2010,
43, 9511–9521.
3) Huan Gao, Guhuan Liu, Xuejun Chen, Zhenhua Hao, Jianyu Tong, Lican Lu,
Yuanli Cai*, Feng Long, Mingqiang Zhu, Media-Modulated Interchain or Intrachain
Coordination of Amphiphilic Block Copolymer Micelles, Macromolecules 2010,
43(14), 6156–6165.
4) Jun Sun, Yifeng Peng, Ying Chen, Yu Liu, Junjie Deng, Lican Lu, Yuanli Cai*, Effect
of Molecular Structure on Thermoresponsive Behaviors of Pyrrolidone-Based
Water-Soluble Polymers, Macromolecules 2010, 43(9), 4041–4049.
5) Junjie Wu, Songmiao Liang, Hongjun Dai, Xiaoyan Zhang, Xiaolan Yu, Yuanli Cai*,
Lina Zhang, Ning Wen, Bin Jiang, Jian Xu*, Structure and properties of
cellulose/chitin blended hydrogel membranes fabricated via a solution pre-gelation
technique, Carbohydrate Polymers 2010, 79, 677–684.
6) Qing Luo, Haimei Zheng, Ye Peng, Gao Huan, Lican Lu, Yuanli Cai*, Facile
Synthesis of Well-Defined pH-Liable Schiff-Base-Type Photosensitive Polymers via
Visible-Light-Activated Ambient Temperature RAFT Polymerization, J. Polym. Sci.,
Part A: Polym. Chem. 2009, 47(23), 6668-6681.
7) Yi Shi, Guhuan Liu, Huan Gao, Lican Lu, Yuanli Cai*, Effect of mild visible light on
rapid aqueous RAFT polymerization of water-soluble acrylic monomers at ambient
temperature: initiation and activation, Macromolecules 2009, 42(12), 3917–3926.
8) Yi Shi, Huan Gao, Lican Lu, Yuanli Cai*, Ultra-fast RAFT Polymerisation of
Poly(ethylene glycol) Acrylate in Aqueous Media under Mild Visible Light Radiation
at 25 oC, Chem. Commun. 2009, 1368-1370.
9) Shanshan Jia, Junjie Fei*, Junjie Deng, Yuanli Cai*, Junan Li, Direct
electrochemistry and electrocatalysis of hemoglobin immobilized in an amphiphilic
diblock copolymer film, Sensors and Actuators B: Chemical 2009, 138(1),
244-250.
10) Chengchu Zeng*, Fujian Liu, Dawei Ping, Liming Hu, Yuanli Cai, Rugang Zhong,
One-Pot Electrochemical Synthesis of Fused Indole Derivatives Containing Active
Hydroxyl Groups in Aqueous Medium, J. Org. Chem. 2009, 74(16), 6386–6389.
11) Chengchu Zeng*, Fujian Liu, Dawei Ping, Yuanli Cai, Rugang Zhong, James Y.
Becker* Electrochemical oxidation of catechols in the presence of
4-amino-3-methyl-5-mercapto-1,2,4-triazole bearing two nucleophilic groups, J.
Electroanal. Chem. 2009, 625, 131-137.
12) Chengchu Zeng*, Fujian Liua, Dawei Ping, Liming Hua, Yuanli Cai, Rugang Zhong,
Electrochemical synthesis of 1,3,4-thiadiazol-2-ylthio-substituted catechols in
aqueous medium, Tetrahedron 2009, 659(23), 4505-4512.
13) Yaohua Li, Yufang Tang, Ke Yang, Xiaoping Chen, Lican Lu, Yuanli Cai*, Facile
synthesis and photo-tunable properties of a photosensitive polymer whose
chromophores bound with pH-labile cyclic acetal linkages, Macromolecules 2008,
41(13), 4597-4606.
14) Junjie Deng, Yi Shi, Wending Jiang, Yifeng Peng, Lican Lu, Yuanli Cai*, Facile
synthesis and thermoresponsive behaviors of a well-defined pyrrolidone based
hydrophilic polymer, Macromolecules 2008, 41(9), 3007-3014.
15) Haijia Zhang, Junjie Deng, Lican Lu, Yuanli Cai*, Ambient temperature RAFT
polymerization of styrene and its functional derivatives under mild long-wave
UV-visible radiation, Macromolecules 2007, 40(26), 9252-9261.
16) Huiwen Yin, Haimei Zheng, Lican Lu, Pengsheng Liu, Yuanli Cai*, Highly efficient
and well controlled ambient temperature RAFT polymerization of glycidyl
methacrylate under visible light radiation, J. Polym. Sci., Part A: Polym. Chem.
2007, 45(22), 5091-5102.
17) Ping Jiang, Yi Shi, Pengsheng Liu, Yuanli Cai*, Synthesis of well-defined glycidyl
methacrylate based block copolymers with self-activation and self-initiation
behaviors via ambient temperature atom transfer radical polymerization, J. Polym.
Sci., Part A: Polym. Chem. 2007, 45(14), 2947–2958.
18) Wending Jiang, Lican Lu, Yuanli Cai*, Highly efficient and well-controlled ambient
temperature RAFT polymerization under solar radiation, Macromol. Rapid
Commun. 2007, 28(6), 725-728.
19) Zhishen Ge, Yuanli Cai, Jun Yin, Zhiyuan Zhu, Jingyi Rao, Shiyong Liu*, Synthesis
and ‘schizophrenic’ micellization of double hydrophilic AB4 miktoarm star and AB
diblock copolymers: structure and kinetics of micellization, Langmuir 2007, 23(3),
1114-1122.
20) Hao Liu, Jian Xu, Jiali Jiang, Jun Yin, Ravin Narain, Yuanli Cai, Shiyong Liu*,
Syntheses and micellar properties of well-defined amphiphilic AB2 and A2B
Y-shaped miktoarm star copolymers of ε-caprolactone and 2-(dimethylamino)ethyl
methacrylate, J. Polym. Sci., Part A: Polym. Chem. 2007, 45(8), 1446-1462.
21) Lican Lu, Haijia Zhang, Nianfa Yang, Yuanli Cai*, Toward rapid and well-controlled
ambient temperature RAFT polymerization under UV-vis radiation: effect of
radiation wave range, Macromolecules 2006, 39(11), 3770-3776.
22) Shaojun Chen, Qi Cao, Bo Jing, Yuanli Cai*, Pengsheng Liu, Jinglian Hu, Effect of
microphase-separation promoters on the shape-memory behavior of polyurethane,
J. Appl. Polym. Sci. 2006, 102(6), 5224-5231.
23) Hongmei Kang, Yuanli Cai*, Junjie Deng, Haijia Zhang,Yufang Tang, Pengsheng
Liu, Synthesis and aqueous solution behavior of phosphonate-functionalized
chitosans, Euro. Polym. J. 2006, 42(10), 2678-2685.
24) Hongmei Kang*, Yuanli Cai, Pengsheng Liu, Synthesis, characterization and
thermal sensitivity of chitosan-based graft copolymers, Carbohydrate Research
2006, 341(17), 2851-2857.
25) Qi Cao*, Yuanli Cai, Bo Jing, Pengsheng Liu, Structure and mechanical properties
of thermoplastic polyurethane, based a hyperbranched polyesters, J. Appl. Polym.
Sci. 2006, 102(6), 5266-5273.
26) Varul Bütün, Shiyong Liu, Jonathon V. M. Weaver, Xavier Bories-Azeau, Yuanli Cai,
Steven P. Armes*, A brief review of ‘schizophrenic’ block copolymers, Reactive &
Functional Polymers 2006, 66(1), 157-165.
27) Lican Lu, Nianfa Yang*, Yuanli Cai*, Well-controlled reversible addition
fragmentation chain transfer radical polymerization under ultraviolet radiation at
ambient temperature, Chem. Commun. 2005, 5287-5288.
28) Syuji Fujii, Yuanli Cai, Jonathan V. M. Weaver, Steven P. Armes*, Synthesis of shell
cross-linked micelles using new acidic ABC triblock copolymers and their
application as pH-responsive particulate emulsifiers, J. Am. Chem. Soc. 2005,
127(20), 7304-7305.
29) Yuanli Cai, Steven P. Armes*, Synthesis of well-defined, Y-shaped zwitterionic block
copolymers via atom transfer radical polymerization, Macromolecules 2005, 38(2),
271-279.
30) Surong Zhou, Haifeng Shi, Ying Zhao, Shichun Jiang, Yonglai Lu, Yuanli Cai, Dujin
Wang*, Charles C. Han, Duanfu Xu, Mesogen-free supramolecular liquid crystalline
state formed by a polyelectrolyte/amphiphile complex, Macromol. Rapid Commun.
2005, 26, 226-231.
31) Yuanli Cai, Yiqing Tang, Steven P. Armes*, Direct synthesis and
stimulus-responsive micellization of Y-shaped hydrophilic block copolymers,
Macromolecules 2004, 37(26), 9728-9737.
32) Yuanli Cai, Steven P. Armes*, A zwitterionic ABC triblock copolymer that forms a
‘trinity’ of micellar aggregates in aqueous solution, Macromolecules 2004, 37(19),
7116-7122.
33) Yuanli Cai, Carine Burguiere, Steven P. Armes*, Direct synthesis and aqueous
solution properties of Y-shaped, stimulus-responsive block copolymer surfactants,
Chem. Commun. 2004, 802-803.
34) Yuanli Cai, Markus Hartenstein, Axel H. E. Müller*, Synthesis of amphiphilic graft
copolymers of n-butyl acrylate and acrylic acid by atom transfer radical
copolymerization of macromonomers, Macromolecules 2004, 37(20), 7484-7490.
35) Surong Zhou, Ying Zhao, Yuanli Cai, Yong Zhou, Dujin Wang*, Charles C. Han,
Duanfu Xu, Supramolecular complexes: lamellar structure and crystalline
transformation, Polymer 2004, 45, 6261–6268.
36) Surong Zhou, Ying Zhao, Yuanli Cai, Dujin Wang*, Duanfu Xu, Lamellar
architecture and crystalline transformation in supramolecular complexes of
highly-branched polyethyleneimine-octadecanoic acid, Chem. Commun. 2003,
1932-1933.
37) Yuanli Cai, Dujin Wang*, Yizhuang Xu, Xianbo Hu, Ying Zhao, Jinguang Wu,
Duanfu Xu, Self-assembled mesomorphic structure of complexes of branched
polyethyleneimine with octadecanoic acid, Macromol. Rapid Commun. 2001, 22
(7), 504-507.
38) Yuanli Cai, Dujin Wang*, Xianbo Hu, Yizhuang Xu, Ying Zhao, Jinguang Wu,
Duanfu Xu, Crystalline polymorphism of alkyl chains in supramolecular complexes
of polyethyleneimine with octadecanic acid, Macromol. Chem. Phys. 2001, 202(11),
2434-2439.
39) Ning Kang, Yizhuang Xu, Yuanli Cai, Weihong Li, Shifu Weng, Lingtao He, Duanfu
Xu*, Jinguang Wu, Guangxian Xu, Different states in orthorhombic crystalline
phase of high density polyethylene, J. Mol. Struct. 2001, 562 (1-3), 19-24.
40) Yizhuang Xu, Roger D. Soloway, Xuexin Liu, Fanxiu Guo, Jinguang Wu*, Yuanli Cai,
Donald M. Taylor, Ying Zhao, Duanfu Xu, Guangxian Xu, Ca2+ clustering and
crystallization of CaCl2 at concentrations below the K-sp in a mucin gel,
Gastroenterology 2001, 120 (5),1061.
41) Ying Zhao, Roger D. Soloway, Limin Yang, Yuanli Cai, Dujin Wang, Shifu Weng,
Jinguang Wu*, Duanfu Xu, Guangxian Xu, L-A-phosphatidylcholine, D-glucose,
and bovine serum albumin each modify the pattern of metal ion deoxycholate
precipitation in agar gel, Gastroenterology 2000, 118(4), A308.
42) Yuanli Cai*, Pengsheng Liu, Xianbo Hu, Dujin Wang, Duanfu Xu,
Microstructure-tensile properties relationships of polyurethane/ poly(urethane
modified bismaleimide-bismaleimide) interpenetrating polymer networks, Polymer
2000, 41(15), 5653-5660.
43) Yuanli Cai*, Pengsheng Liu, Synthesis and characterization of polyurethane/poly
(urethane modified bismaleimide- bismaleimide) IPNs, Chin. Chem. Lett. 2000,
11(6), 525-526.
44) Yuanli Cai*, Zhongming Jiang, Dafong Yang, Pengsheng Liu, Structure and
Thermal Properties of PU/P(BMI-UBMI) IPNs, J. Appl. Polym. Sci. 1998, 68(10),
1689-1694.

 
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