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白如科教授

( 2010-11-14 )
 

白如科理学博士

中科院软物质化学重点实验室

高分子科学与工程系

教授 博士生导师

Tel: +86-551-63600722 (Office)

Fax: +86-551-63631760

E-mail: bairk@ustc.edu.cn

 

Research Group Webpage:

http://staff.ustc.edu.cn/~bairk

个人简介

1978年11月毕业于中国科学技术大学高分子化学专业后留校任教,1984年12月获中国科学技术大学理学硕士学位,1989年9月获中国科学院北京化学研究所理学博士学位。1989年11月起为中国科学技术大学材料科学与工程系讲师,1995年6月为高分子科学与工程系副教授,2002年1月晋升为教授,同时被聘为博士生导师。曾于1989年、1992年、1996年和1998年在日本早稻田大学和东京大学做短期研究工作。

 

研究方向

1. 活性/可控聚合反应

2. 新型聚合物的设计与合成

3. 超分子自组装与功能、智能高分子材料

4. 探针和传感器分子合成与性质

5. 氟烯烃可控自由基聚合及氟聚合物性能 

 

科研项目

  1. γ-射线辐照活性自由基聚合研究,国家自然科学基金项目(2002-2005,已结题)。
  2. 两亲性超分子星形聚合物的设计与自组装特性研究,国家自然科学基金项目(2005-2007,已结题)。
  3. 两亲性超分子星形聚合物的自组装研究, 高等学校博士点基金(2005-2007,已结题)。
  4. 叠氮和羰基叠氮烯类单体的设计合成与活性自由基聚合研究,国家自然科学基金项目(2007-2009,已结题)。
  5. 仿生智能响应性分子体系的设计及合成,科技部973项目子项目(2007CB936401,在研项目,参加者)。
  6. 含氟乙烯和含氟丙烯的活性/可控自由基超支化聚合反应研究,国家自然科学基金项目国家基金(2010-2012)
  7. 季铵碱含氟聚合物的自由基聚合合成方法及性能研究,国家自然科学基金项目(2011-2013)。

 

教学工作

曾主讲课程本科生课程《聚合反应原理》和《专业英语及文献》,现在主讲本科生核心课程《高分子化学》及研究生课程《聚合反应原理专论》。参与本科教材《高分子化学》和《硕士研究生入学考试化学类科目考试纲要》的编写,均由中国科学技术大学出版社出版。《高分子化学》获本校优秀教材2等奖。

 

获奖及荣誉  

1995年获安徽省科技进步二等奖,1998年获国家技术发明四等奖,1996年获校优秀教学奖,1998年获校优秀教师奖,2008年获“杨亚校友--爱岗敬业奖”。

 

近期代表性论文

  1. Yinyin Bao, Hu Wang, Qianbiao Li, Bin Liu, Qing Li,  Wei Bai, Bangkun Jin, and Ruke Bai*. 2,2′-Biimidazole-Based Conjugated Polymers as a Novel Fluorescent Sensing Platform for Pyrophosphate Anion. Macromolecules 2012, DOI:10.1021/ma300361t.
  2. Fanfan Du, Jiao Tian, Hu Wang,  Bin Liu, Bangkun Jin and Ruke Bai*, Synthesis and Luminescence of POSS-Containing Perylene Bisimide-Bridged Amphiphilic polymers. Macromolecules 2012, DOi: 10.1021/ma300100s.
  3. Yinyin Bao,Bin Liu, Fanfan Du,Jiao Tian, Hu Wang and Ruke Bai* , A New Strategy for Highly Selective Fluorescent Sensing F- and Zn2+ with dual output modes. J. Mater. Chem. 2012, 22, 5291-5294.
  4. Yanxue Wang, Xinle Li, Fanfan Du, Hansen Yu, Bangkun Jin and Ruke Bai*, “Use of Alcohols as Reducing Agents for Synthesis of Well-Defined Polymers by AGET-ATRP” Chem. Commun., 2012, 48, 2800-2802.
  5. Bin Liu, Hu Wang, Taisheng Wang, Yinyin Bao, Fanfan Du, Jiao Tian, Qianbiao Li, Ruke Bai* “A new ratiometric ESIPT sensor for detection of palladium species in aqueous solution”, Chem. Commun., 2012, 48, 2867-2869.
  6. Bin Liu, Yinyin Bao, Hu Wang, Fanfan Du, Jiao Tian, Qianbiao Li, Taisheng Wang, Ruke Bai* “An efficient conjugated polymer sensor based on the aggregation-induced fluorescence quenching mechanism for specific detection of palladium and platinum ions” Journal of Materials Chemistry, 2012, 22,3555-3561.
  7. Yinyin Bao, Qianbiao Li, Bin Liu, Fanfan Du, Jiao Tian, Hu Wang, Yanxue Wang and Ruke Bai*. “Conjugated polymers containing a 2, 2'-biimidazole moiety—a novel fluorescent sensing platform”, Chem. Commun., 2012, 48, 118–120.
  8. Haiting Zheng, Xiaodong Ye,Hu Wang, Lifeng Yan, Ruke Bai*,and Wanqun Hu,“A facile one-pot strategy for preparation of small polymer nanoparticles by self-crosslinking of amphiphilic block copolymers containing acyl azide groups in aqueous media”,Soft Matter, 2011, 7, 3956–3962.
  9. Yinyin Bao, Bin Liu, Hu Wang, Jiao Tian and Ruke Bai*, “A ‘‘naked eye’’ and ratiometric fluorescent chemosensor for rapid detection of F- based on combination of desilylation reaction and excited-state proton transfer”, Chemical Communications, 2011, 47, 3957–3959.
  10. Bin Liu, Yinyin Bao, Fanfan Du, Hu Wang, Jiao Tian and Ruke Bai*, “Synthesis and characterization of a fluorescent polymer containing 2,6-bis(2-thienyl)pyridine moieties as a highly efficient sensor for Pd2+ detection”, Chemical Communications, 2011, 47, 1731–1733.
  11. Lei Liu, Dan Lu, Hu Wang, Qibao Dong, Pucheng Wang and Ruke Bai*, “Living/controlled free radical copolymerization of chlorotrifluoroethene and butyl vinyl ether under 60Co γ-ray irradiation in the presence of S-benzyl O-ethyl dithiocarbonate”, Chemical Communications, 2011, 47, 7839-7841.
  12. Fanfan Du, Hu Wang, Yinyin Bao, Bin Liu, Haiting Zheng and Ruke Bai*,“Conjugated Coordination Polymers Based on 8-Hydroxyquinoline Ligands: Impact of Polyhedral Oligomeric Silsesquioxanes on Solubility and Luminescence”, Journal of Materials Chemistry, 2011, 21,10859-10864.
  13. Bin Liu, Huiguang Dai, Yinyin Bao, Fanfan Du, Jiao Tian and Ruke Bai*, “2,6-Substituted pyridine derivative-containing conjugated polymers: synthesis, photoluminescence and ion-sensing properties”, Polymer Chemistry, 2011, 2, 1699-1705.
  14. Yinyin Bao, Bin Liu, Hu Wang, Fanfan Du and Ruke Bai*, “A highly sensitive and selective ratiometric Cd2+ fluorescent sensor for distinguishing Cd2+ from Zn2+ based on both fluorescence intensity and emission shift”,Analytical Methods, 2011, 3, 1274-1276.
  15. Guang Li, Hu Wang, Haiting Zheng, and Ruke Bai*, “A Facile Approach for the Fabrication of Highly Stable Superhydrophobic Cotton Fabric with Multi-Walled Carbon Nanotubes-Azide Polymer Composites”, Langmuir2010, 26(10), 7529–7534.
  16. Yun Wang, Qibao Dong, Yanxue Wang, Hu Wang, Guang Li, Ruke Bai*, “Investigation on RAFT Polymerization of a Y-Shaped Amphiphilic Fluorinated Monomer and Anti-Fog and Oil-Repellent Properties of the Polymers”, Macromol. Rapid Communication2010, 31(20), 1816–1821.
  17. Guang Li, Hu Wang, Haiting Zheng, Ruke Bai*, “Room-Temperature RAFT Copolymerization of 2-Chloroallyl Azide with Methyl Acrylate and Versatile Applications of the Azide Copolymers”, Journal of Polymer Science: Part A: Polymer Chemistry, 2010, 48(6), 1348–1356.
  18. Guang Li, Haiting Zheng, Yanxue Wang, Hu Wang, Qibao Dong, Ruke Bai*, “ A facile strategy for the fabrication of highly stable superhydrophobic cotton fabric using amphiphilic fluorinated triblock azide copolymers”, Polymer, 2010, 51(9), 1940-1946.
  19. Dairen Lu, Yun Wang, Kang Tao, Ruke Bai*, “Synthesis of Amphiphilic Supramolecular Miktoarm Star Copolymers by Molecular Recognition”, Macromol. Rapid Commun., 2009, 30(2), 104–108
  20. Guang Li, Haiting Zheng, Ruke Bai*, “A Facile Strategy for the Preparation of Azide Polymers via Room Temperature RAFT Polymerization by Redox Initiation”,Macromol. Rapid Commun., 2009, 30(6), 442-447.
  21. Liang Zhang, Dairen Lu, Kang Tao, Ruke Bai*, “Synthesis, Characterization and Self-Assembly of Novel Amphiphilic Block Copolymers with a Polyhedral Oligomeric Silsesquioxanes Moiety Attached at the Junction of the Two Blocks”, Macromol. Rapid Commun., 2009, 30(12),1015-1020.
  22. Yun Wang, Lu Lu, Hu Wang, Dairen Lu, Kang Tao, Ruke Bai*, “A Facile Strategy for Preparation of a-Heterobifunctional Polystyrenes with Well-Defined Molecular Weight”, Macromol. Rapid Commun., 2009, 30(22), 1922-1927.
  23. Haiting Zheng, Wei Bai, keliang Hu, Ruke Bai*, Caiyuan Pan Facile Room Temperature RAFT Polymerization via Redox Initiation J. Polym. Sci., Part A, Polym. Chem., 2008, 46, 2575-2580.
  24. Dairen Lu, Yun Wang, Tianyuan Wu, Kang Tao, Lijia An, Ruke Bai*, “A Strategy for Synthesis of Ion-Bonded Amphiphilic Miktoarm Star Copolymers Via Supramolecular Macro-RAFT Agent”, J. Polym. Sci.,Part A: Polym. Chem. 2008, 46, 5805–5815.
  25. Dairen Lu, Kang Tao, Yun Wang, Ruke Bai*, “Synthesis, Characterization, and Self-Assembly of Ion-Bonded A2B Rod-Coil Copolymer with ligo(para-phenylene- ethynylene) as Rod Segment”, J. Polym. Sci., Part A, Polym Chem., 2008, 46, 7667–7676.
  26. Kang Tao, Dairen Lu, Ruke Bai,* Hongfei Li, Lijia An, “ A Strategy for Synthesis of Ion-Bonded Supramolecular Star Polymers by Reversible Addition- Fragmentation Chain Transfer (RAFT) Polymerization”, Macromol. Rapid Commun., 2008, 29, 1477–1483.
  27. Wei Bai, Liang Zhang, Ruke Bai,* Guangzhao Zhang, “ A Very Useful Redox Initiator for Aqueous RAFT Polymerization of N-Isopropylacrylamide and Acrylamide at Room Temperature”, Macromol. Rapid Commun. 2008, 29, 562-566.
  28. Haiting Zheng, Daoben Hua, Ruke Bai*, Keliang Hu, Lijia An, Caiyuan Pan, “ Controlled/Living Free Radical Copolymerization of 4-(Azidocarbonyl) Phenyl Methacrylate with Methyl Acrylateunder 60Co γ-Ray Irradiation”, J. Polym. Sci., Part A, Polym Chem., 2007, 45, 2609.
  29. Daoben Hua*, Xueping Ge, Jing Tang, Xiulin Zhu, Ruke Bai*, Caiyuan Pan Low-Temperature Controlled Free-Radical Polymerization of Vinyl Monomers in the Presence of a Novel Cyclic Dixanthate under c-Ray Irradiation J.Polym.Sci.,Part A: Polym. Chem., 2007, 45, 2847–2854.
  30. Kui Xu, Yun Wang, Yanxue Wang, Tao Yu, Lijia An, Caiyuan Pan, Ruke Bai*, “Synthesis and characterization of ABC ternary segregated H-shaped copolymers”, Polymer, 2006, 47(13), 4480.
  31. Daoben Hua, Kun Cheng,Wei Bai, Ruke Bai*, Weiqi Lu, Caiyuan Pan, “A Strategy for Developing Novel Structural Polyurethanes and Functional Materials. Controlled/Living Free Radical Polymerization of Acryloyl Azide under 60Co-Ray Irradiation”, Macromolecules, 2005, 38, 3051-3053.
  32. Daoben Hua, Wei Bai, Junpeng Xiao, Ruke Bai*, Weiqi Lu, Caiyuan Pan, “ A Strategy for Synthesis of Azide Polymers via Controlled/living Free Radical Polymerization of Allyl Azide under 60Co -Ray Irradiation”, Chemistry of Materials, 2005, 17, 4574-4576.
  33. Kui Xu, Yun Wang, Ruke Bai*, Weiqi Lu, Weiqi; Caiyuan Pan, “Synthesis of Amphiphilic Rod-coil ABC Triblock Copolymers with OPE as the Middle Rigid Block”, Polymer, 2005, 46, 7572-7577.
  34. Daoben Hua, Xueping Ge, Ruke Bai*, Weiqi Lu, Caiyuan Pan, “Controlled/ living” Free-Radical Polymerization of Methyl Acrylate under 60Co γ-Ray Irradiation. Structure Effect of Z-Group”, Polymer, 2005, 46, 12696-12702.

 
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